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Paper degradation

The natural aging of paper

Paper has naturally in its composition elements which, when aging, are degrading and take part to artwork’s weakening. Paper is mainly constituted of cellulose fibers. The natural aging process slowly and irreversibly breaks molecules constituting paper fibers.
The damaging degree and speed depends in the one hand on the chemical instability of the materials that constitute the paper and on the other hand on the external factors of degradation as the environment, the storage conditions and the handling. Initially, linen, hemp and cotton rags were used to make paper.
In the middle of 19th century, the use of wooden fibers created an important fall of the paper quality. Those papers are made up of lots of impurities and the fibers used are much shorter than before. The result of this is a greater weakness and a lesser good conservation in time. The new sizing process using alum and rosin as well as the use of chemicals to bleach some paper pastes are also responsible of this instability.

The degradation of papier

Temperature and humidity

High temperature speeds up the unstable materials degradation which are part of the artwork but also in the media. Combined to high humidity, it favours also mold growing. In the opposite, low temperature makes the paper crumbly. A too sudden change in temperature can cause physical degradations like cracks or detachments. Likewise, a too sudden change of humidity causes size variations also leading to cracks, detachments or deformations.

Light


Light from sun or lamp essentially emits two kinds of radiations, both dangerous for artworks :
  • Infrared rays : they are present in great quantity in day light, they produce an elevation of temperature and have a drying effect on organic materials, like paper, aging will be then faster.
  • Ultraviolet rays : they are present in great quantity in light produced by halogen and fluorescent lamps, and in a lesser quantity in day light. They cause, for example, the yellowing of artworks exposed.

Mold

The mold which is able to grow on artworks is fungus and bacteria. Those organisms feed themselves from materials that they damage. Bacteria are capable of degrading many materials by modifying and weakening them. Most of the molds are developing between 4 and 30°C, and only when relative humidity exceeds 60%. Degradations observed are the appearance of indelible stains of various colours and a weakening of the paper, until sometimes its complete destruction.

Insects


Some conditions are favourable to the developpment of insects. In order to eat, they are attacking objects or documents containing cellulose. High temperature and humidity, bad ventilation, insufficient and irregular cleaning, presence of food, bad tightness of doors and windows, bad state of the building and the entrance of contaminated objects in the environment are the main causes of insects development. Degradations caused by insects are progressive and can go from simple holes til total destruction of the artwork. Insects use organic materials to nourish themselves and to nest. They cause physical damages when they deposit their eggs (galleries) and chemical damages when their larvae are growing up. The latters secrets substances which degrade organic material in order to make it eatable.

Pollution

Pollution can be gas or solid particles, both dangerous for artworks. Gaseous pollution is one of the first external causes of chemical degradation. Among the most corrosive pollutants in a city’s air, there are sulphured compounds (sulphur dioxide and sulphur trioxide), nitrogened compounds like nitrogen oxide or ozone. Those compounds react with the air’s humidity and create compounds speeding the degradation of artworks. Mineral, metallic or organic particles can help in catalyzing some degradation process. They can also help the growing of mold, always present in the atmosphere (pollen, spores…).

Man’s action

Several degradations are linked with the bad handling of artworks. For instance, handling of a drawing with only one hand can provoke twists, creating folds on the artwork. Likewise, two drawings put down on one another, without interleaving, can create rubbings and a wear of the media. These bad habits may lead to the appearance of stains and tears. Finally, consolidations or restorations done by inexperienced can cause deteriorations beyond repair.